Diffusion-controlled rate constant of electron transfer at the oil|water interface
نویسندگان
چکیده
منابع مشابه
Diffusion-controlled reactions: Upper bounds on the effective rate constant
For a diffusion-controlled reaction in a static, reactive bed of nonoverlapping spherical traps, upper bounds on the effective reaction-rate constant have been obtained from a variational principle of Rubinstein and Torquato. The bounds remain finite for all volume fractions and arbitrary distributions of traps. We have obtained two kinds of bounds: one kind depends on the trap volume fraction ...
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ژورنال
عنوان ژورنال: Journal of Electroanalytical Chemistry
سال: 2004
ISSN: 1572-6657
DOI: 10.1016/j.jelechem.2004.05.010